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M. Gauvin, F. Buch, L. Delevoye and S. Harder, Chem. – Eur. , 2009, 15, 4382–4393. 15. S. I. Wolke, R. Buffon and U. P. R. Filho, J. Organomet. , 2001, 625, 101–107. 16. L. Zhong, M. Y. Lee, Z. Liu, Y. J. Wanglee, B. Liu and S. L. Scott, J. , 2012, 293, 1–12. 17. S. L. Scott, A. Fu and L. A. MacAdams, Inorg. Chim. Acta, 2008, 361, 3315– 3321. 18. M. O. de Souza, R. F. de Souza, L. R. Rodrigues, H. O. Pastore, T. M. Gauvin, J. M. R. Gallo and C. Favero, Catal. , 2013, 32, 32– 35. 19. M. O. de Souza, L.

J. Sunley, J. Am. Chem. , 2004, 126, 13391–13399. 51. V. Dufaud, G. P. Niccolai, J. Thivolle-Cazat and J. M. Basset, J. Am. Chem. , 1995, 117, 4288–4294. View Online 11:24:22. 1039/9781782628439-00001 Synthesis of Well-defined Solid Catalysts by Surface Organometallic Chemistry 25 52. M. Chabanas, E. A. Quadrelli, B. Fenet, C. Coperet, J. -M. Basset, A. Lesage and L. Emsley, Angew. , Int. , 2001, 40, 4493–4496. 53. N. Merle, M. Taoufik, M. Nayer, A. Baudouin, E. Le Roux, R. M. Gauvin, F. Lefebvre, J.

16,42 An important point to note is that these techniques are complementary to each other and thus multiple techniques are required to characterize supported metal complex catalysts. In addition, it is important to understand the limitations of each technique. For example, EXAFS provides direct information about local structures around a particular atom regardless of the phase of the materials. 43,44 However, it gives average information of the whole sample. Therefore, characterization of zeolite-supported metal complexes consisting of View Online 32 11:25:09.

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