Download Contemporary Metal Boron Chemistry I: Borylenes, Boryls, by Holger Braunschweig, Carsten Kollann, Fabian Seeler (auth.), PDF
By Holger Braunschweig, Carsten Kollann, Fabian Seeler (auth.), Todd B. Marder, Zhenyang Lin (eds.)
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Additional info for Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane σ-Complexes, and Borohydrides
Sample text
Platinum Complexes . . . . . . . Mono(boryl) Complexes . . . . . . Bis(boryl) Complexes . . . . . . Semi-Bridging Ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 100 103 103 109 111 9 Group 11 (Copper, Silver and Gold) . . . . . . . . . . . 112 10 Outlook . . . . . . . . . . . . . . . . . . . 113 References . . . . . . . . . . . . .
11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. Timms PL (1967) J Am Chem Soc 89:1629 Timms PL (1973) Acc Chem Res 6:118 Pachaly B, West R (1984) Angew Chem Int Ed 23:454 Braunschweig H (1998) Angew Chem Int Ed 37:1786 Irvine GJ, Lesley MJG, Marder TB, Norman NC, Rice CR, Robins GR, Roper WR, Whittell GR, Wright LJ (1998) Chem Rev 98:2685 Braunschweig H, Colling M (2001) Coord Chem Rev 223:1 Aldridge S, Coombs DL (2004) Coord Chem Rev 248:535 Braunschweig H, Colling M (2000) J Organomet Chem 614/615:18 Braunschweig H, Colling M (2003) Eur J Inorg Chem 393 Braunschweig H, Rais D (2005) Heteroatom Chem 16:566 Braunschweig H (2004) Adv Organomet Chem 51:163 Ehlers AW, Baerends EJ, Bickelhaupt FM, Radius U (1998) Chem Eur J 4:210 Radius U, Bickelhaupt FM, Ehlers AW, Goldberg N, Hoffmann R (1998) Inorg Chem 37:1080 Macdonald CLB, Cowley AH (1999) J Am Chem Soc 121:12113 Boehme C, Uddin J, Frenking G (2000) Coord Chem Rev 197:249 Braunschweig H, Kollann C, Rais D (2006) Angew Chem Int Ed 45:5254 Braunschweig H, Kollann C, Englert U (1998) Angew Chem Int Ed 37:3179 Braunschweig H, Colling M, Kollann C, Stammler HG, Neumann B (2001) Angew Chem Int Ed 40:2298 Uddin J, Boehme C, Frenking G (2000) Organometallics 19:571 Chen Y, Frenking G (2001) J Chem Soc Dalton Trans 434 Cowley AH, Lomelí V, Voigt A (1998) J Am Chem Soc 120:6401 Greiwe P, Bethäuser A, Pritzkow H, Kühler T, Jutzi P, Siebert W (2000) Eur J Inorg Chem 9:1927 Braunschweig H, Herbst T, Rais D, Seeler F (2005) Angew Chem Int Ed 45:7461 Braunschweig H, Colling M, Hu C, Radacki K (2003) Angew Chem Int Ed 42:205 Erker G, Pfaff R, Krüger C, Werner S (1991) Organometallics 10:3559 Braunschweig H, Colling M, Kollann C, Merz K, Radacki K (2001) Angew Chem Int Ed 40:4198 Uddin J, Frenking G (2001) J Am Chem Soc 123:1683 Coombs DL, Aldridge S, Jones C, Willock DJ (2003) J Am Chem Soc 125:6356 Coombs DL, Aldridge S, Rossin A, Jones C, Willock DJ (2004) Organometallics 23:2911 Coombs DL, Aldridge S, Jones C (2002) J Chem Soc Dalton Trans 20:3851 Kays DL, Day JK, Ooi LL, Aldridge S (2005) Angew Chem Int Ed 44:7457 Aldridge S, Jones C, Gans-Eichler T, Stasch A, Kays DL, Coombs ND, Willock DJ (2006) Angew Chem Int Ed 45:6118 Braunschweig H, Radacki K, Seeler F, Whittell GR (2006) Organometallics 24:4605 Braunschweig H, Radacki K, Scheschkewitz D, Whittell GR (2005) Angew Chem Int Ed 44:1658 Braunschweig H, Whittell GR (2005) Chem Eur J 11:6128 Braunschweig H, Radacki K, Seeler F, Whittell GR (2004) Organometallics 23:4178 Irvine GF, Rickard CEF, Roper WR, Williamson A, Wright LJ (2000) Angew Chem Int Ed 39:948 Tilley TD (1991) In: Patai S, Rappoport Z (eds) The Silicon-Heteroatom Bond, chaps 9 and 10.
BNMe2 ){(η5 -C5 H5 )Mn(CO)2 }2 ] [45, 46] and [{µ-BN(SiMe3 )2 }(µ-CO) {(η5 -C5 H4 Me)Fe(CO)}2 ] [55], for which the structural parameters are in agreement with the presence of a formally sp2 -hybridized boron atom. Assuming the same hybridization of the boron atom in 48, the orthogonal disposition of the amino substituent would rule out any effective N–B π-donation, and should result in considerable elongation of the N–B bond distance. 3(6) pm), thus indicating significant double bond character of the B–N linkage.