By J.?M. Lehn(eds.)
This ebook covers significant periods of crystals within the layout of novel fabrics, with an emphasis on advances and applications.
* The editor is likely one of the pioneers within the "design" and "engineering" procedure in stable kingdom supramolecular chemistry
* All authors built a particular type of crystals and are international leaders within the field
* displays the fast growth made during this fieldContent:
Chapter 1 Hydrogen Bonds in Inorganic Chemistry: program to Crystal layout (pages 1–75): Lee Brammer
Chapter 2 Molecular reputation and Self?Assembly among Amines and Alcohols (Supraminols) (pages 77–151): Raffaele Saladino and Stephen Hanessian
Chapter three Very huge Supramolecular drugs according to Hydrogen Bonding (pages 153–175): Jerry L. Atwood, Leonard J. Barbour and Agoston Jerga
Chapter four Molecular Tectonics: Molecular Networks in keeping with Inclusion methods (pages 177–209): Julien Martz, Ernest Graf, Andre De Cian and Mir Wais Hosseini
Chapter five Layered fabrics by way of layout: 2nd Coordination Polymeric Networks Containing huge Cavities/Channels (pages 211–239): Kumar Biradha and Makoto Fujita
Chapter 6 the development of One?, ? and Three?Dimensional Organic–Inorganic Hybrid fabrics from Molecular construction Blocks (pages 241–274): Robert C. Finn, Eric Burkholder and Jon A. Zubieta
Chapter 7 A Rational process for the Self?Assembly of Molecular development Blocks within the box of Molecule?Based Magnetism (pages 275–323): Melanie Pilkington and Silvio Decurtins
Chapter eight Polymorphism, Crystal adjustments and Gas–Solid Reactions (pages 325–373): Dario Braga and Fabrizia Grepioni
Chapter nine Solid–Gas Interactions among Small Gaseous Molecules and Transition Metals within the sturdy country. towards Sensor functions (pages 375–386): Michel D. Meijer, Robertus J. M. Klein Gebbink and Gerard van Koten
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Additional info for Crystal Design: Structure and Function, Volume 7
They note that while synthon I results from combination with the square-planar [MCl4 ]2À anion, neither synthon I nor II arises when tetrahedral [MCl4 ]2À or octahedral [MCl6 ]2À anions are used, in contrast to the use of the [H2 (DABCO)]2 cation by Brammer et al. Importantly, however, their studies indicate that all of the 4, 4H -bipyridinium structures can be rationalized as belonging to a larger homologous family of salts that include chloride and a variety of chlorometallates as counteranions [42c].
1 Anionic bridges Since the most common combination in coordination chemistry, that of metal cation and neutral ligands, gives rise to cationic coordination complexes, it is no surprise that the choice of anion should be of utmost important in designing hydrogen-bonded networks based upon coordination compounds as building blocks. 2, where anions were often selected to minimize the chance of their forming (accepting) hydrogen bonds and thus maximize the chance of direct hydrogen bonding between the cationic building blocks.
In this case, the [2 Â 2] coordination grids assemble via hydrogen bonds in only one direction; in the orthogonal direction p±p edge±face and face±face interactions are the principal cohesive forces. Reproduced from with permission of Wiley-VCH. In exploring the chemistry of octahedral [Mo6 Cl8 X6 ]2À clusters, Shriver and co-workers prepared the cluster in which XÀ p-OC6 H4 CONH2 À , each carboxamide-bearing ligand being terminally bound to one of the metal centres . The two crystal structures reported as different solvates, [(crypt)Na]2 [Mo6 Cl8 X6 ] Á2DMF Á 6H2 O Á 4CH3 OH and [(crypt)Na]2 [Mo6 Cl8 X6 ] Á 6DMF, adopt lamella structures, although with different cluster-to-cluster separations within and between layers.