Download Inorganic Glasses for Photonics: Fundamentals, Engineering, by Animesh A. Jha, Peter Capper, Safa Kasap, Arthur Willoughby PDF

By Animesh A. Jha, Peter Capper, Safa Kasap, Arthur Willoughby

Complicated textbook on inrganis glasses compatible for either undergraduates and researchers.

Engaging variety to facilitate understanding

Suitable for senior undergraduates, postgraduates and researchers getting into fabric technology, engineering, physics, chemistry, optics and photonics fields

Discusses new options in optics and photonics together with updates on diagnostic techniques

Comprehensive and logically dependent

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Additional info for Inorganic Glasses for Photonics: Fundamentals, Engineering, and Applications

Example text

These ionic bond dominated sulfide structures are conditional glass formers. A vast majority of chalcogenide glasses follow the (8 N) or “octet” rule, originally proposed by Professor Sir Neville Mott, who was rewarded with a shared Nobel Prize in Physics with Dr Phillip Warren Anderson at Bell Laboratories and Professor John Hasbrouck van Vleck at Harvard University for “their fundamental theoretical investigations of the electronic structure of magnetic and disordered systems”. This groundbreaking discovery has since revolutionized microelectronics and now has an impact on nano-scale electronics, which can be found in Mott’s Nobel lecture on “Electrons in Glass” [73].

12a and b, which define the TeO2-Li2O-R(Zn,Ba,Pb)O and TeO2-Al2O3-R(Li,Na,K)2O sections. These ternary compo­ sitions are one of the glass-forming systems investigated in detail for fibre and planar glass based device engineering. 4 Fluoride and Halide Network Forming and Conditional Glass-Forming Systems The BeF2 based glasses were the very first type of fluoride glasses, which were studied in the context of using the fluoroberyllate liquid as coolants for the fuel core in nuclear power plants. Beryllium fluoride has a similar structure to that of the [SiO4]4 tetrahedron because the ratio of Be2+ and F ions is too small for the stabilization of structures, namely bipyramids and octahedral.

G. 2 it is qualitatively apparent that the entropy of fusion scales with the partial charge on oxygen and with Pauling’s and Sanderson’s electro­ negativity. The glass-forming network compounds have smaller values of δO and entropy of fusion, in general. This trend seems to apply satisfactorily to all glass-forming networks for which the values of δO are known, which helps in understanding the chemical character of various compounds that partake in the constitution of a glass. 3 also includes data for chlorides, for which a comparable trend amongst network formers, contributors and modifiers is apparent, especially when comparing the residual charge on chloride ions in BeCl2 and CdCl2.

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