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By Childress, Solward
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Extra resources for On the Rapid generalization of magnetic fields
Sample text
6 .... 2 .... ~ A(vasym. CH 3) / A (usym. 4 A plot of the absorbance ratio A(vsym. A(vasym. CH2) in CC14 solution for C5H12 to C18H38. CH3)/A(vsym. CH2) vs the absorbance ratio A(vasym. 0 rsym. 0 8 1312J~----'~--. . _--. 8 . 4 vasym. 5 Plots of vasym. CH2 vs vsym. 6 mol % CDC13/CC14, and CDC13 solutions. 5 ! 2 ! 4 . 6 . 8 . 2 . 4 . 6 . 6 2959,8 v a s y m . 6 Plots of vasym. CH3 vs vsym. 6 mol % CDC13/CC|4, and CDC13 solutions. 6- ...... 5- 0,asym. ocn2Y,c~-I (~a. 0- ; . 4 I ....... 6 (vasym. CH3)- I ........
CH3 str. CH3 str. CH3 str. CH3 str. CH3 str. CH3str. CH3 str. CH3 str. CH3 str. 2 bending IR absorbance data for n-alkanes: a. 3 CDCI3 Alkyl Carbon-Hydrogen Vibrations IR data for a. CH2 str. CH2 str. CH2 str. CH2 str. CH2 str. CH2 str. CH2 str. CH2 str. CH2 str. CH2 str. 4 The frequency separation between the a. CH3 and the a. /'~ o o 9 c; o O0 d 9 d ,---~ c~ d t'~ 0 0 o 0000 0 d 0 c~ ~ d ~ 0 c~ c~Ooc;O 0 0 0 0 0 O O d o . d O0 o 0 ~ . 0 0 I Alkyl Carbon-Hydrogen Vibrations . d o c~ o O0 c~ d ~'~1 0 ~ .
Thus, the polarization of the electron cloud during the vC--C vibration is larger for the trans isomer than it is for the cis isomer. Comparison of the Raman data for 1-octene and 1-decene shows that vC=C occurs at 1642 c m - 1 ; however, it is noted that the band intensity is 8 for 1-octene and 5 for 1-decene. The empirical structure for 1-octene is CH3-(CH2)5-CH=CH2 and for 1-decene is CH3-(CH2)F-CH=CH2. The CH2 groups are in a 5 : 7 in this case while the band intensity is in an 8 : 5 for vC=C.