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By C. K. Jorgensen, E. Nieboehr, R. Reisfeld
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A. The Variation Principle and the LCAO Model . . . . . . . . . . . . . . . IV. SO 69 69 B. The I m p o r t a n c e of Kinetic E n e r g y . . . . . . . . . . . . . . . . . . . 75 C. Comparison 77 with Copper(ll) Complexes .................................. References ............................................................... 78 49 C. K. Jorgensen I. One-electron Substitutions in the Lowest Configuration A. Monatomic Entities It is an empirical fact that the lowest 20 to 400 J-levels of gaseous atoms or of positive ions M +~ can be classified (1) as belonging to electron configurations.
This is not altogether surprising since earlier work (98) had indicated a marginal difference in the mode or position of binding of RE ions relative to Ca+2. In contrast to Ca+z, the lanthanide ions at pH 7 induced perturbations of tyrosyl electronic transitions and rendered the lanthanide nuclease complex resistant to trypsin digestion. This difference was also reflected in the inhibitory action of the RE ions in the Ca+2 generated nuclease activity. 4 A, respectively, from the bound Ca +z in the active site.
Proc. Natl. Acad. Sci. US 71, 359 (1974). 216. Miehaelson, D. , Horwitz, A. , Klein, ]~I. : Biochemistry 12, 2637 (1973). 217. , Sokoloski, E. , Brewer, H. : Proc. Natl. Acad. Sci. S. 71, 549 (1974). 218. Williams, R. J. : In: Proc. 4 t h Int. Congr. ). Basel, Switzerland: Schwabe 1969. 219. Andrews, S. , Faller, J. , Gilliam, J. , Barrnett, R. J. : Proc. Natl. Acad. Sci. S. 70, 1814 (1973). 220. Barry, C. , Glasel, J. , Williams, R. J. , Xavier, A. V. : J. Mol. Biol. 84, 471 (1974). 221. Barry, C.