Download Hypercarbon Chemistry by George A. Olah PDF
By George A. Olah
The basic re-creation of the e-book that positioned hypercarbon chemistry at the mapA finished and modern remedy of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) in the direction of electrophiles, Hypercarbon Chemistry, moment variation bargains with all significant features of such chemistry serious about hydrocarbon differences, and of the structural and response chemistry of carboranes, combined hydrides during which either carbon and boron atoms perform the polyhedral molecular frameworks.Despite the firmly verified tetravalency, carbon can bond at the same time to 5 or extra different atoms. "Hypercarbon" bonding permeates a lot natural, inorganic and organometallic chemistry, and the booklet serves because the compendium for this phenomenon.Copious diagrams illustrate the wealthy number of hypercarbon buildings referred to now, and styles therein. person chapters take care of particular different types of compound (e.g. organometallics, carboranes, carbocations) or differences that continue via brief hypercarbon species, detailing primary chemistry, together with reactivity, selectivity, stereochemistry, mechanistic elements and extra.
Read Online or Download Hypercarbon Chemistry PDF
Similar industrial & technical books
Multivariate Datenanalyse GERMAN
In vielen Fachgebieten, wie z. B. der Lebensmittelchemie, der pharmazeutischen oder biotechnologischen Industrie fallen immer mehr Daten an, die ausgewertet werden m? ssen. Klassische Verfahren gelangen hierbei schnell an ihre Grenzen. Die multivariate Datenanalyse besch? ftigt sich mit Verfahren, mit denen guy aus einer F?
Content material: Enzymes for fuels and chemical feedstocks / okay. Grohmann and Michael E. Himmel -- Enzymes in pulp and paper processing / L. Viikari, A. Kantelinen, M. Rättö, and J. Sundquist -- Enzymes for anaerobic municipal reliable waste disposal / Christopher J. Rivard, William S. Adney, and Michael E. Himmel -- Thermostable saccharidases : new assets, makes use of, and biodesigns / J.
- Initiation of Polymerization
- Introduction to chemicals from biomass
- Introduction to Conductive Polymer Composites
- Toxicogenomics: A Powerful Tool for Toxicity Assessment
- Solid acid catalysts
Extra info for Hypercarbon Chemistry
Sample text
Bottom: allowing for resonance between the four (C5H5+) or five (C6Me62+) ways of allocating such bond networks to these pyramidal species generates the following two-center bond orders (numbers of electron pairs per C–C link). 18. MO diagrams showing how neutral C4H4 and cationic C5H5+ and C6Me62+ would be antiaromatic if polygonal. MO treatments are preferred in such cases. The manner in which these same cations, (C5H5)+ and (C6Me6) 2+, can be treated in MO terms is worth illustrating here for the purpose of comparison with the localized bond schemes just discussed, and also to underline the relationship between these pyramidal systems and normal aromatic ring systems.
Albright, W. M. Butler, T. J. Anderson, M. D. Glick, and J. P. Oliver, J. Am. Chem. Soc. 98, 3995 (1976). 36. B. Morosin and J. Howatson, J. Organomet. Chem. 29, 7 (1971). 37. R. P. Kirchen and T. S. Sorensen, J. Chem. Soc. Chem. Commun. 769 (1978). 38. S. Masamune, M. Sakai, H. Ona, and A. L. Jones, J. Am. Chem. Soc. 94, 8956 (1972). 39. A. V. Kemp-Jones, N. Nakamura, and S. Masamune, J. Chem. Soc. Chem. Commun. 109 (1974). 40. H. Hogeven and P. W. Kwant, Acc. Chem. Res. 8, 413 (1975). 41. S. Masamune, M.
G. A. Stone, and E. W. , Pergamon Press, Oxford, 1982, Vol. 5, pp. 459–542. 57. L. J. Todd, in Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone, and E. W. , Pergamon Press, Oxford, 1982, Vol. 6, pp. 543–554. 58. R. N. , Metal Interactions with Boron Clusters, Plenum Press, New York, 1982. 59. R. E. Williams, Chem. Rev. 92, 177 (1992). 34 INTRODUCTION: GENERAL ASPECTS 60. J. , The Borane, Carborane, Carbocation Continuum, Wiley, New York, 1998. 61. R. N. Grimes, J. Chem. Educ.