Download Metal organic frameworks as heterogeneous catalysts by Fransesc Llabrés i Xamena; Jorge Gascon PDF

By Fransesc Llabrés i Xamena; Jorge Gascon

Content material: creation; half A. SYNTHESIS AND CHARACTERIZATION OF MOFs; Synthesis of MOFs; Post-synthetic amendment of MOFs; Characterization of MOFs. 1. mixed Vibrational and digital Spectroscopies; Characterization of MOFs. 2. lengthy and native diversity Order Structural choice of MOFs by means of Combining EXAFS and Diffraction strategies; MOFs for power and Environmental functions; Computational method of Chemical Reactivity of MOFs; CATALYSIS by means of MOFs

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Mesopor. , 2010, 129, 287. 6. K. Sumida, S. Horike, S. S. Kaye, Z. R. Herm, W. L. Queen, C. M. Brown, F. Grandjean, G. J. Long, A. Dailly and J. R. Long, Chem. , 2010, 1, 184. 7. R. Banerjee, A. Phan, B. Wang, C. Knobler, H. Furukawa, M. O’Keeffe and O. M. Yaghi, Science, 2008, 319, 939. 8. S. Bauer, C. Serre, T. Devic, P. Horcajada, J. Marrot, G. Ferey and N. Stock, Inorg. , 2008, 47, 7568. 9. P. Maniam and N. Stock, Inorg. , 2011, 50, 5085. 10. M. Eddaoudi, J. Kim, N. L. Rosi, D. T. Vodak, J. Wachter, M.

1039/9781849737586-00031 32 Chapter 3 many desired functionalities are either not tolerant to the conditions used for MOF synthesis (typically solvothermal) or non-innocent, and hence lead to changes in the nature of the network formed. Post-synthetic (or postsynthetic) modification (PSM) provides an alternative strategy to forming functionalised MOFs. In this approach, the nature of the pores is altered after synthesis of the MOF, thus allowing sensitive and/or coordinating groups to be introduced into the pores of a pre-formed network structure.

88. T. Ahnfeldt, D. Gunzelmann, J. Wack, J. Senker and N. Stock, CrystEngComm, 2012, 14, 4126. 1039/9781849737586-00031 CHAPTER 3 Post-synthetic Modification of MOFs ANDREW D. 1 These materials are referred to by a number of different names including coordination polymers and metal organic frameworks (MOFs) and, although there is debate about how interchangeable these are,2,3 this review uses the term ‘metal organic framework’ for any type of coordination network structure, regardless of the nature of the ligands.

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