Download Molecular Recognition and Polymers: Control of Polymer by Vincent Rotello, Sankaran Thayumanavan PDF

By Vincent Rotello, Sankaran Thayumanavan

Cutting-edge strategies for tapping the gigantic power of polymers using particular non-covalent interactions to regulate polymer constitution and homes is a swiftly rising box with purposes in various disciplines. Molecular popularity and Polymers covers the basic points and functions of molecular recognition—in the production of novel polymeric fabrics to be used in drug supply, sensors, tissue engineering, molecular imprinting, and different components. This reference starts off by way of explaining the basics of supramolecular polymers; it progresses to hide polymer formation and self-assembly with a large choice of examples, after which contains discussions of biomolecular attractiveness utilizing polymers. With chapters contributed via the key specialists of their fields, this resource:

  • presents an built-in source for supramolecular chemistry, polymer technology, and interfacial technology
  • Covers complex, state of the art concepts utilized in the layout and characterization of non-covalent interactions in polymers
  • Illustrates the best way to tailor the houses of polymeric fabrics for varied purposes

Stand-alone chapters handle particular functions independently for simple reference. it is a most effective source for graduate scholars and researchers in polymer chemistry, supramolecular chemistry, fabrics technological know-how, and actual natural chemistry.

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10 Design of supramolecular block copolymers based on the 6-H bonded heteroduplex 15†16. Mixing three templated PS chains with three complementarily templated PEG chains leads to nine block copolymers. 11 GPC traces of 15c†16c, 15c, and 16c eluted with DMF/toluene (10/ 90, v/v, left) and DMF (right) at 60 8C. 12 (a) AFM image of spin-cast 15d†16d from benzene showing cylindrical nanodomains from the microphase separation of the supramolecular block copolymer and (b) AFM image of spin-cast 15b†16b from benzene showing self-assembled fibers.

D. in 1990 from Yale University with Harry Wasserman in the area of natural products synthesis. From 1990 – 93, he was an NSF postdoctoral fellow with Julius Rebek Jr. T. in the area of host-guest chemistry. Since 1993, Professor Rotello has been at the University of Massachusetts at Amherst as an Assistant Professor from 1993 – 1998, Associate Professor (1998 – 2001), Professor (2001–2005), and Charles A Goessmann Professor of Chemistry (2005–). ) His research program spans the areas of devices, polymers, nanotechnology, and biological systems, with over 245 papers and one book (Nanoparticles: Building Blocks for Nanotechnology, Kluwer: New York, 2004) published to date.

1 that includes hydrophobic interactions, which are dealt with in more detail in Chapter 2. In this chapter, we present a brief overview of supramolecular polymers and polymerization and supramolecular interactions of polymer side chains. We provide examples of the control over the solution state polymer structure that can be achieved at the molecular level and then extended to micro- and macroscale assemblies. Molecular Recognition and Polymers: Control of Polymer Structure and Self-Assembly. Edited by V.

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