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By D. Bryce-Smith

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Selective enhancement of room temperatures phosphorescence i s achieved by cyclodextrin treated cellulose s u b s t r a t e s 3 4 7 . surface active a g e n t ~ 3 ~and ~ , for heterocyclic compounds by absorption on silica gel coated plates submerged in (~hlorofoi-m-containing solvents349. Delayed fluorescence can occur during deactivation o f highly excited triplet states3”. Energy is transferred to the m e d i u m , which may be an electron acceptor andlor d o n o r . Extended and localised triplet states in disordered media can be examined by optical and ESR t e c h n i q u e ~ 3 ~.

A r e v i e w of photoinduced electron transfer and electron acceptor complexes usefully surveys the s u b j e ~ t ’ ~ ’ Details . o f the mechanisms can be obtained by very short t i m e resolution spectroscopy. Dynamic solvent effects on intramolecular electron- transfer involve solvent fluctuations. Time resolved ps emission spectroscopy has been used t o examine t h e kinetics o f intramolecular c h a r g e transfer in b i s ( 4 - a m i n o p h e n y 1 ) s u l p h o n e i n ethanol a s a function o f temperature i n this respect162.

A t high temperature excited Photochemistry 24 state transfer i s incoherent and excitation i s localised on a given site in the lattice and then randomly hops. At l o w temperatures phonon interactions are reduced and coherent states become important. These states are no longer localised and energy transfer occurs by propagation o f excitation wavepackets. At very l o w temperatures the polariton structure involves an interaction of the whole m a t e r i a l with the illuminating electromagnetic field.

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